Not tested myself but isn‘t the id to be supposed to be 9d? AFAIR according to the NIST standard, slots have a designated use case like 9c for digital signing such as signing S/MIME e-mail, 9d for decryption of encrypted S/MIME e-mail.
Does writing the cert to the slot using nitropy work?
I tried to test your issue as I am also interested to learn about possible uses of my Nitrokeys but I currently have no PIV enabled firmware installed.
I know from other tokens that the tooling always is a bit troublesome and often requires vendor tools to manage them. I had good results with the tool pivy back then but it was no Nitrokey I experimented with.
Export the public key ($ nitropy nk3 piv --experimental read-certificate --key 9c --path ma_cle_publique.crt)
Not sure all of this is correct and it seems that the certificate could be lost in a firmware update which is worrying if a local backup cannot be done, but at least it seems to work (i checked with Evolution and later in Thunderbird)